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Vibrational spectra


The vibrational transitions of H continue to be a popular topic among infrared spectroscopists. A highlight is the definite detection of interstellar H by Geballe & Oka in absorption in the direction of deeply embedded protostars. H infrared emission lines were also detected in polar regions of Saturn. The lines are weaker than those in Jupiter by two orders of magnitude reflecting the lower plasma activity. On the spectroscopic side, Oka and co-workers have observed the near-infrared 3 overtone band of H at 1.4 m using InGaAsP communication diode lasers. Spectral lines and the distribution of H in extremely high rotational levels have been studied for supplying data to astronomers. New experiments and analysis of the H vibration-rotation spectra were also made by the NRC group in Canada, and by Maier's group. Spin selection rules in plasma chemistry of ortho- and para-H has been experimentally demonstrated.


Oka also reported on the infrared spectra of several other ions. The spectrum of NH in highly-excited vibrational states up 10600 cm has been observed and analyzed, as has the hot band of NH and the infrared spectrum of NH. The infrared spectrum of CH involving high rotational levels has been observed and the rotational distribution studied. The spectrum of CH was measured using a hollow cathode discharge, and its chemistry analyzed.


The infrared work at the Herzberg Institute of Astrophysics has concentrated on the spectra of weakly-bonded complexes, including CO-N, CO-He, and the HD dimer. Fundamental infrared spectroscopy has been performed for the band of C isotopes, C, CHNC, CHOH isotopes, CH and isotopes, and CO. High resolution wavenumber standards for the infrared have been published.


Bernath and co-workers have used the Fourier transform method to measure the infrared spectra of a large number of stable and unstable species, including ND, PH, hot HO, HF, SiO, CS, and SH. Pure carbon molecules, including C and C have been discussed.


Theoretical calculations of ground state potential energy surfaces and dipole moments have been made for CO, MgO, NO, SiO, and CH. Theoretical infrared spectra for PAH's (neutral, cations and anions) have been computed by Langhoff.




next up previous
Next: Rotational spectra Up: WORKING GROUP 5: Previous: Electronic spectra



Jim Esmond
Wed Oct 30 13:33:17 EST 1996