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WORKING GROUP 5: MOLECULAR STRUCTURE AND TRANSITION DATA

E.F. van Dishoeck, Chair
Leiden Observatory
P. O. Box 9513
2300 RA Leiden
The Netherlands


The most significant development in the last three years has been the enormous expansion and availability of atomic and molecular databases in electronic form (CD-ROM, ftp, World-Wide-Web). Millions of molecular lines ranging from the millimeter to the extreme ultraviolet part of the spectrum can now be accessed on-line, and improved software allows rapid searches through the data bases. At the same time, the astrophysical needs for such large data bases have increased considerably. Spectral line surveys at submillimeter wavelengths typically contain thousands of rotational lines, high resolution infrared spectra from the ground and the Infrared Space Observatory require large amounts of information on the vibrational transitions, whereas large format CCDs in the optical and ultraviolet allow large wavelength ranges to be scanned for electronic transitions. The astrophysical modeling has improved to the stage that highly accurate molecular data are essential. A well-known example, which has been studied intensively by several groups over the last decade, is provided by the VUV electronic transitions of CO. For models of cool stars and brown dwarfs, information on the weaker transitions, whose intensities are five orders of magnitude less than those of the strongest transitions, proves to be essential.


There have been significant developments in the experimental techniques and theoretical methods for determining molecular structure, both of stable species, and of radicals and ions. Of particular interest is the progress in measuring and calculating the spectra of large molecules, including PAH's, long carbon chains and C.


The following summary is based on contributions sent to me by U.G. Jørgenson, T. Oka, J.P. Phillips, F. Rostas, P.L. Smith, and P. Thaddeus in the summer of 1996. Other topics have been added through a literature search. This report focuses on the highlights, and concerns only molecules of astrophysical interest. No attempt has been made to provide a complete overview or list of references. For further information on a specific molecule, the bi-monthly Berkeley Newsletter continues to be a good starting point. The printed Newsletter is essentially a bibliography of articles in the current journals on molecules comprising four or fewer atoms (contact jphillips@astro.berkeley.edu or spdavis@physics.berkeley.edu).






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Next: Electronic spectra Up: No Title Previous: References WG4



Jim Esmond
Wed Oct 30 13:33:17 EST 1996