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CHEMICAL REACTIONS

The following table of measurements of reaction rates at low temperatures was provided to W. H. Parkinson by Ewine F. van Dishoeck.

*** IMPORTANT: The following table will not be correct when viewed with the Mosaic viewer. ***

 

Reaction T range Type Reference

CN + O$$₂ 99-761 K cell Sims & Smith 1988, Chem. Phys. Lett. 151, 481.

CN +NO + M 99-450 K cell Sims & Smith 1993, J. Chem. Soc. Faraday Trans. 89, 1.

OH + HCl, C$$₂H$$₆ 138-298 K cell Sharkey & Smith 1993, J. Chem. Soc. Faraday Trans. 89, 631.

OH + CH$$₄ 178-298 K

OH + CO 80-298 K cell Frost et al. 1993, J. Phys. Chem. 97, 12,254.

CN + O$$₂ 13-295 K CRESU Sims et al. 1994, J. Chem. Phys. 100, 4,229.

CN + NH$$₃ 25-295 K

CN + C$$₂H$$₂, C$$₂H$$₄, C$$₂H$$₆ 25-298 K combined Sims et al. 1993, Chem. Phys. Lett. 211, 461.

CN + CH$$₄, C$$₃H$$₆ 160-298 K cell

OH + N 103-294 K cell Smith & Stewart 1994, J. Chem. Soc. Faraday Trans. 90, 3,221.

OH + O 158-294 K

OH + but-1-ene, 23-295 K CRESU Sims et al. 1994, J. Chem. Soc. Faraday Trans. 90, 1,473. (E- & Z-) but-2-ene

OH + HBr 23-295 K CRESU + Sims et al. 1994, J. Chem. Phys. 101, 1,748. theoretical

OH + NO + M 23-301 K combined Sharkey et al. 1994, J. Chem. Soc. Faraday Trans. 90, 3,609.

80-295 K cell Islam et al. 1994, J. Phys. Chem. 98, 9,285.

energy transfer Islam et al. 1995, J. Chem. Phys. 103, 9,676.

CH + O$$₂, NO 13-708 K combined Bocherel et al. 1996, J. Phys. Chem. 100, 3,063.

CH + NH$$₃ 23-295 K CRESU

CH + N 216-584 K cell Brownsword et al. 1996, J. Chem. Soc. Faraday Trans. 92, 723.

CH(v=1) + CO, N$$₂ 23-584 K combined Herbert et al., J. Phys. Chem., submitted.

CH + CH$$₄, C$$₂H$$₂, C$$₂H$$₄ 23-295 K CRESU Canosa et al., A & A, submitted. C$$₂H$$₆ and but-1-ene

CH + H$$₂ goes to CH$$₃ theoretical Brownsword et al., ApJ, in preparation. by radiative assn.

CH(v=0,1) + H$$₂, D$$₂ 13-744 K combined Brownsword et al., J. Chem. Phys., in preparation.

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